Sintesis Zif-8 Dengan Metode Solvotermal Dalam Pelarut Etanol Dan Dimetilformamida

Pradipta Pangastuti, Muhammad Nadjib Mudjahid, Ratna Ediati
Submission Date: 2015-02-04 14:33:06
Accepted Date: 2015-03-16 09:16:43

Abstract


Sintesis material kristal ZIF-8 menggunakan metode solvotermal dalam media etanol:N-N,dimetilformamida  pada suhu 120 °C selama 40 jam dengan variasi perbandingan pelarut 0, 1:9, 2:8, 3:7, 4:6, 5:5 dan 7:3 telah berhasil dilakukan. Karakteristik ZIF-8 hasil sintesis berdasarkan kristalinitas dengan XRD menunjukkan puncak karakteristik pada semua sampel pada daerah 2θ sebesar 7,3; 10,3; 12,7; 16,4 dan 18,0°. Hasil karakterisasi dengan FTIR membuktikan terbentuknya ZIF-8 dengan munculnya spektra pada bilangan gelombang 420 cm-1 yang mengindikasikan terjadinya ikatan antara seng dan nitrogen. Hasil dengan SEM menunjukkan morfologi permukaan paling baik pada ZIF-8(3:7) berbentuk segi empat

Keywords


ZIF-8; Etanol:DMF; karakterisasi

References


Rosi, N.L, Eckert J., Eddaoudi M., Vodak D.T., Kim J., O’Keeffe M., Yaghi O.M. (2013). Hydrogen storage in microporous metal-organic frameworks. Science., 300, 1127-1129.

Maji T.K., Matsuda R., Kitagawa S., (2007). Photoactivation Of A Nanoporous Crystal For On-Demand Guest Trapping And Conversion. Nat. Mater., 6, 142–148.

Li J., Kuppler R.J., Zhou H.C., (2009). Selective Gas Adsorption And Separation In Metal–Organic Frameworks. Chem. Soc., 38, 1477–1504

Yuan B., Pan Y., Li Y., Yin B., Jiang V. (2010). A Highly Active Heterogeneous Palladium Catalyst for the Suzuki–Miyaura and Ullmann Coupling Reactions of Aryl Chlorides in Aqueous Media. Chem. Int. Ed., 49, 4054–4058

Zhang M., Guan J., Zhang B., Su D., Williams C.T., Liang C., (2012). Chemical Vapor Deposition of Pd(C3H5)(C5H5) to Synthesize Pd@MOF-5 Catalysts for Suzuki Coupling Reaction. Catal. Lett., 142, 313–318

Jiang, D., Mallat, T., Krumeich, F. & Baiker, A. (2011). Polymer-Assisted Synthesis Of Nanocrystalline Copper-Based Metal-Organic Framework For Amine Oxidation. Catal. Commun., 12 (7), 602-05.

Guo, H. L., Zhu, Y. Z., Wang, S., Su, S. Q., Zhou, L., Zhang, H. J., (2012). Combining Coordination Modulation with Acid-Base Adjustment for the Control over Size of Metal-Organic Frameworks. Chem. Mater., 24 (3), 444-450.

Taylor-Pashow KML, Della Rocca J, Xie Z, Tran S, Lin W. (2009). Postsynthetic modifications of iron-carboxylate nanoscale metal-organic frameworks for imaging and drug delivery. J Am Chem Soc., 131, 14261–14263.

Zacher D., Shekhah O., Wöll C., Fischer R. A. (2009).

Thin films of metal-organic frameworks

Chem. Soc., 38, 1418-1429.

Jiang H.L., Akita T., Ishida T., Haruta M., Xu Q., Am J. (2011). Synergistic catalysis of Au@Ag core-shell nanoparticles stabilized on metal-organic framework. Chem. Soc., 133 1304–1306.

Moggach, Stephen A., Bennet, Thomas D., Cheetham, Anthony K. (2009). The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1,47 GPa. Angewandte Chem., 121, 7221-7223.

Nguyen, L.T. L., Le, K.K.A., Phan, N.T.S. (2012). A Zeolitic Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation. Chin. Journal Of Catalysis., 33, 688-696.

Zhang, Z., Xian, S., Xi, H., Wang, H., Li, Z. (2011). Improvement of CO2 Adsorption on ZIF-8 Crystals Modified by Enhancing Basicity of Surface. Chemical Engineering Science., 66, 4878-4888.

Phan, A., Doonan, C.J., Uribe-Romo, Fernando J., Knobler, C.B., O’Keeffe, M., Yaghi, O.M. (2009). Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks. Accounts of Chemical Research., 43, 58-67.

Park, K. S., Ni, Z., Cote, A. P., Choi, J. Y., Huang, R., Uribe-Romo, Fernando J., Chae, Hee K., O’Keeffe M., Yaghi, Omar M. (2006). Exceptional Chemical and Thermal Stability of Zeolitic Imidazolate Frameworks. Proceeding of the National Academy of Sciences., 103, 27.

Fairen-Jimenez, D, Moggach, SA, Wharmby, MT, Wright, PA, Parsons, S & Düren, T (2011). Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations, American Chemical Society., 133, 23, 8900-8902.

Phan, A., Doonan, C.J., Uribe-Romo, Fernando J., Knobler, C.B., O’Keeffe, M., Yaghi, O.M. (2009). Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks. Accounts of Chemical Research., 43, 58-67.

Mulyati, T.A. (2014). Aktivasi Karbon Berpori Bertemplat MOF-5 Menggunakan KOH sebagai Material Penyimpan Hidrogen. Thesis Kimia Institut Teknologi Sepuluh Nopember

Venna, Surendar R., Carreon, Moises A. (2009) Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO2/CH4 Separation. J. AM. CHEM. SOC 132, 76-79.

Cravillon, J., Schruder, C.A., Bux, H., Rothkirch, A., Caro, J., Wiebcke, M. (2011) Formate Modulated Solvothermal Synthesis of ZIF-8 Investigated Using Time-Resolved In Situ X-ray Diffraction and Scanning Electron Microscopy. The Royal Society of Chemistry. 12, 2086-2090.

Park, K. S., Ni, Z., Cote, A. P., Choi, J. Y., Huang, R., Uribe-Romo, Fernando J., Chae, Hee K., O’Keeffe M., Yaghi, Omar M. (2006). Exceptional Chemical and Thermal Stability of Zeolitic Imidazolate Frameworks. Proceeding of the National Academy of Sciences., 103, 27.

Nguyen, L.T. L., Le, K.K.A., Phan, N.T.S. (2012). A Zeolitic Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation. Chin. Journal Of Catalysis., 33, 688-696.

Zhang, Z., Xian, S., Xi, H., Wang, H., Li, Z. (2011). Improvement of CO2 Adsorption on ZIF-8 Crystals Modified by Enhancing Basicity of Surface. Chemical Engineering Science., 66, 4878-4888.

Park, K. S., Ni, Z., Cote, A. P., Choi, J. Y., Huang, R., Uribe-Romo, Fernando J., Chae, Hee K., O’Keeffe M., Yaghi, Omar M. (2006). Exceptional Chemical and Thermal Stability of Zeolitic Imidazolate Frameworks. Proceeding of the National Academy of Sciences., 103, 27.

Venna, Surendar R., Carreon, Moises A. (2009) Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO2/CH4 Separation. J. AM. CHEM. SOC 132, 76-79.

Cravillon, J., Schruder, C.A., Bux, H., Rothkirch, A., Caro, J., Wiebcke, M. (2011) Formate Modulated Solvothermal Synthesis of ZIF-8 Investigated Using Time-Resolved In Situ X-ray Diffraction and Scanning Electron Microscopy. The Royal Society of Chemistry. 12, 2086-2090.

Pan, Y., Liu, Y., Zeng, G., Zhao, L., Lai, Z. (2011). Rapid Synthesis of Zeolitic Imidazolate Framework-8 (ZIF-8) Nanocrystals in an Aqueous System. Chem. Communication., 47, 2071-2073.

Seoane B., Zamaro J.M., Tellez C., Coronas J., (2012). Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20) Crys. Eng. Commun., 14, 3103–3107

Bao Q., Lou Y., Xing T., Chen J., (2013). Rapid Synthesis Of Zeolitic Imidazolate Framework-8 (ZIF-8) In Aqueous Solution Via Microwave Irradiation. Inorg. Chem. Commun., 37, 170–173

Yamamoto D., Maki T., Watanabe S., Tanaka H., Miyahara M.T., Mae K., (2013). Synthesis and adsorption properties of ZIF-8 nanoparticles using a micromixer. Chem. Eng. J., 227, 145–150.

Yang L., Lu Chin H., (2012). Microwave-assisted Ionothermal Synthesis and Characterization of Zeolitic Imidazolate Framework-8. Chem J., 30–5, 1040–1044

Venna, S.R., Jasinski, J.B., Carreon, M. A. (2010). Structural Evolution of Zeolitic Imidazolate Framework-8. Journal of American Chemical Society., 132, 18030-18033.

Nguyen, L.T. L., Le, K.K.A., Phan, N.T.S. (2012). A Zeolitic Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation. Chin. Journal Of Catalysis., 33, 688-696

Ordoñez, M. J. C., Balkus, K. J., Ferraris, J. P. dan Musselman, I. H. (2010). Molekular sieving realized with ZIF-8/Matrimid mixed-matrix membranes. Journal of Membrane Science., 361, 28–37.

Lanchas, M., Vallejo-Sanchez, D., Beobide G., Castillo, O., Aguayo, A.T., Luque, A., Roman P., (2012). A direct reaction approach for the synthesis of zeolitic imidazolate frameworks: template and temperature mediated control on network topology and crystal size. Chem. Commun., 48, 9930-9932.


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