Sintesis Ni-UiO-66 SecaraSolvotermal

Irma Rahmawati, Afifah Rosyidah, Ratna Ediati
Submission Date: 2015-02-05 13:01:45
Accepted Date: 2015-03-16 09:16:43

Abstract


Material UiO-66 dan Ni-UiO-66 telah berhasil disintesis secara solvotermal pada suhu 120°C selama 24 jam.Material hasil sintesis dianalisis dengan XRD, FTIR, SEM-EDX, TGA dan adsorpsi desorpsi isotermal N2.Difraktogram semua padatan hasil sintesis menunjukkan puncak utama pada 2θ sebesar 7,4°dan 8,5° yang sama dengan puncak karakteristik material UiO-66 standar. Spektra FTIR dari material UiO-66 dan Ni-UiO-66 hasil sintesis menunjukkan puncak serapan pada bilangan gelombang yang sama dengan material UiO-66 standar. Foto SEM dari material UiO-66 dan Ni-UiO-66 hasil sintesismenunjukkan morfologi kristalberbentuk kubus. Kurva isotermal adsorpsi N2 menghasilkanluas permukaan BET material UiO-66 dan Ni-UiO-66 hasil sintesisberturut-turut yaitu 841,299 dan 819,299 m2/g.

Keywords


Solvotermal;UiO-66; Ni-UiO-66; kristalinitas; luas permukaan

References


Cavka, J.H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, Carlo., Bordiga, S., Lillerud, K.P., (2008). “A New Zirconium Inorganic Building Brick Forming Metal Organic Framework with Exceptional Stability”. Journal of The American Chemical Society 130, 13850-13851.

Zhao, Q., Yuan, W., Liang, J., Li, J., (2013).“Synthesis and Hydrogen Storage Studies of Metal-Organic Framework UiO-66”.International Journal of Hydrogen Energy, 1-6.

Low, J.J., Benin, A.I., Jakubczak, P., Abrahamian, J.F., Faheem, S.A., Willis, R.R. (2009). Journal of the American Chemical Soiety 131, 15834–15842.

Chuah, G.K., Liu, S.H., Jaenicke, S., Horrison, L.J., (2001). “Cyclisation of Citronellal to Isopulegol Catalysed by Hydrous Zirconia and Other Solid Acids”.Journal of Catalyst 200, 352-359.

Abid, H.R., Tian, H., Ang, H-M., Tade, M.O., Buckley, C.E., Wang, S., (2012).“Nanozise Zr-Metal Organic Framework (UIO-66) for Hydrogen and Carbon Dioxide Storage”.Chemical Engineering Journal 187, 415-420.

Yang, J-M., Liu, Q., Sun, W-Y., (2014). “Shape and Size Control and Gas Adsorption of Ni(II)-doped MOF-5 Nano/Microcrystals”. Microporous and Mesoporous Materials 190, 26-31.

Yudianto, D., Ediati, R., (2014). “Sintesis dan Karakterisasi Ni-ZIF-8”. Institut Teknologi Sepuluh Nopember. Surabaya.

Kim, J., Kim, Se-Na, Jang, Hoi-Gu, Seo, G., Ahn, Wha-Seung. (2013). “ CO2 Cycloaddition of Styrene Oxide Over MOF Catalysts”. Applied Catalysis A:General453, 175-180.

Venna, S.R., Jasinski, J.B., Carreon, M.A., (2010). “Structural Evolution of Zeolitic Immidazolate Framewok-8”.Journal of the American Chemistry Society 132, 18030-18033.

Suhiwa, K., Patah, A., Onggo, A., (2011). “Sintesis Metal Organic Frameworks (MOFs) dari Niobium (V) Oksida dan Asam Benzena 1,4-dikarboksilat”. Prosiding Simposium Nasional Inovasi Pembelajaran dan Sains, ISBN :978-602-19655-0-4, 242-247.

Pavia, D.L., Lampman, G.M., Kriz, G.S., Vyvyan, J.R., (2009). “Introduction to Spectroscopy : 4e”. Departement of Chemistry Western Washington University Bellingham, Washington.

Rahmawati, I.D., Ediati, R., Prasetyoko, D., (2014). “Synthesis of UiO-66 Using Solvothermal Method at High Temperature”.International Seminar on Applied Technology Science and Art 4th, 191.


Full Text: PDF

CC Licencing


Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).

Refbacks

  • There are currently no refbacks.


Lembaga Penjaminan Mutu, Pengelolaan dan Perlindungan Kekayaan Intelektual (LPMP2KI) ITS
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.